@ cybernescence that has worked, makes sense really, I wasn't sure if GG actually set up the x file itself or not. Obviously not, lol.
@ Pirate Myke, Alphas don't seem to make a difference with or without, or at least I haven't spotted anything yet.
I do however have an issue with it still. I guessed the images needed in place of the originals and it seems I have guessed correcly as the images all seem to be in the right place. However the entire image looks like a normal map...
I'm fairly certain that I saved them all as diffuse, but as I generally have to use mindtex for saving dds files, it can sometimes do odd things when saving over files. I will have to double check them if I can, Gimp seems to refuse to display them and also the original images although I have the plugin for dds textures enabled.
Hopefully have it sussed now though thanks for the help everyone!
SPECS: Q6600 CPU. Nvidia 660GTX. 8 Gig Memory. Win 7.